![]() To see him in the locker room getting taped up and having to take naps because he was tired and beat up and have to get up the next day and go out and fight, that was our culture. "So it goes beyond just the numbers, it goes beyond just what you see on the stat sheet. He had to overcome a lot of stigmas and a lot of stereotypes to prove himself in this league," George said. "We saw all he had to go through to get to that point as an African-American quarterback. The Titans cheered McNair for 10 minutes when then-coach Jeff Fisher announced McNair had been voted MVP. George recalled all that McNair went through with injuries, thoughts of retiring to dramatic comebacks such as coming off the bench for a divisional win in Pittsburgh in 2000. Asked for a favourite game moment for McNair, George said when the quarterback was named MVP. George, who won the Heisman Trophy while at Ohio State, called a wild-card playoff victory over Baltimore in January 2004 as his favourite personal memory. McNair earned three of his four Pro Bowls with the Titans and shared The Associated Press' NFL MVP with Peyton Manning in 2003 as the first black quarterback to win that award. McNair remains one of only three quarterbacks in NFL history to throw for 30,000 yards and run for 3,500 yards with Fran Tarkenton and Steve Young. 9 will forever be held in the highest regard in the Titans nation." ![]() It is a tangible reminder for me and the boys to know that No. "Retiring his jersey is a really big deal for us. "Steve would be truly honoured to know that he was held in such high esteem by you," Mechelle McNair wrote. Team announcer Mike Keith read a statement she sent. Mechelle McNair, his widow, was not able to attend Wednesday's news conference. 625 winning percentage with only one losing season at 7-9 in 2001 and the 2000 Super Bowl, two AFC championship games, four playoff appearances and two division titles. McNair and George together went 80-48 for a. McNair, killed July 4, 2009, leads the franchise with 76 wins as a starter. 3 overall, played 11 of 13 seasons here and remains the franchise's second all-time leading passer (27,141 yards) behind only Pro Football Hall of Fame quarterback Warren Moon (33,685). McNair, drafted a year before in 1995 at No. George, who played eight seasons with this team and made four Pro Bowls, remains both the franchise's all-time leading rusher with 10,009 yards and all-time scrimmage yards leader with 12,153. It's totally appropriate to have us go in together." "I couldn't imagine having a day like this where my jersey (is) retired by myself," George said. George called having his number retired a "huge honour" considering that usually requires being in the Pro Football Hall of Fame. McNair and George will join six other former Titans and Oilers whose numbers have been retired including Warren Moon, Earl Campbell, Mike Munchak, Bruce Matthews and Elvin Bethea - all members of the Pro Football Hall of Fame. ![]() 9 or 27, giving the league 153 numbers that have been retired. The Titans say this will be the first time an NFL team has retired either a No. ![]() ![]() "This is a big moment for me personally because I love these guys, and I know my dad loved these guys and he will be so happy and proud that we were honouring them today," Strunk said of her late father, Bud Adams, who founded the franchise in 1960. 15 at their home opener against the Indianapolis Colts. 9 of the late Steve McNair again, players who helped the franchise through its difficult relocation from Houston to Tennessee to its lone Super Bowl berth.Ĭontrolling owner Amy Adams Strunk announced Wednesday that the franchise will retire both numbers Sept. NASHVILLE - Nobody with the Titans will ever wear Eddie George's No. ![]()
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![]() ![]() I think the hybridization of SO2 is clear from both the explained concepts. Here cationic and anionic charges will be 0 as it’s a neutral compound. M is the count of monovalent atoms presentīy the same token H = 5, its Sp4 hybridization.Īnd finally, when, H is 6, it will be Sp3d2 hybridization.įor SO2, the number of valence electrons of the S atom = 6 and the number of monovalent atoms = 0, because oxygen is a divalent atom.The formula for finding hybridization of any compound is There’s an image attached below for better understanding. Well, those two (i.e one of the 3p orbital and another electron in 3d) formed the ? bonds between sulfur and oxygen. Thinking about the other 2 electrons of 3p which were not associated with hybridization? ![]() And the resting 2 paired orbitals form the lone pair of sulfur. Now, the 3s2 and 3p3 associate to form Sp2 hybridization with 3 equivalent orbitals, containing 2 paired electrons and 2 unpaired.įor forming 2 sigma bonds with oxygen atoms, sulfur needs the 2 unpaired electrons from the Sp2 hybridized orbitals. When in an excited state, one electron from 3px, motions to 3d orbital. I would advise understanding the theory first and then you can absolutely go for the formula.Ī quick edge for you, when 1 s orbital unites with 2 p orbitals it derives in Sp2 hybridization having 3 equivalent orbitals.Īs well, in case of SO2, the ground state electronic configuration is 1s2 2s2 2p6 3s2 3p4. Now hybridization of SO2 can be discerned in two ways, one is the theory and the 2nd is straight applying the formula. The next topic we need to know is the hybridization of SO2. Oxygen has 2 lone pairs and sulfur has 1 lone pair.Īt last, do n’t forget to confirm the formal charge of all the atoms! This will lastly complete the octet of the atoms. We need to put these remaining electrons around the atoms as per the need. Thus the number of electrons employed in double bonds = 8ĭeducting that from the total valence electrons we get 10 electrons remaining. There are 2 oxygen atoms in the compound, thus = 6*2 = 12Īfter drawing the skeletal structure, we can see that none of the atoms can achieve their octet with single bonds. In SO2, the sulfur’s valence electron = 6 Now let’s see the lewis structure of SO2. ![]() The total number of bonding electrons around the boron is 8 (full octet). The number of non-bonded electrons is zero. The number of valence electrons for boron is 3. This formula explicitly indicates the relationship between the number of bonding electrons and their link to how many are formally “ kept ” by the atom.įor example, applying this to BH4 we get: Step 6 – At last, it’s important to analyze if all the atoms are having their lowest possible formal charge.įormal charge calculation can be done using:-įormal charge = –.Step 5 – Giving double or triple bonds is fundamental if it is needed for fulfilling the octet rule for all atoms.Always start with the electronegative atoms then bring them to the electropositive ones. Step 4 – Next, our work is achieving the octet of the atoms with the resting electrons, after the formation of the single bonds.Step 3 – The third step is building a skeleton structure with single bonds only.The atom with the highest number of binding locations is the central atom. Step 2 – Next thing is determining the central atom.A ‘+’ sign implies losing electrons and ‘-‘ means gaining. While doing so, do take care of the +, – signs. Step 1 – Figuring out the total number of valence electrons in the molecule is the first and most remarkable step. ![]() ![]() ![]() The timestamp is only as accurate as the clock in the camera, and it may be completely wrong. If the file has been modified from its original state, some details such as the timestamp may not fully reflect those of the original file. ![]() This file contains additional information such as Exif metadata which may have been added by the digital camera, scanner, or software program used to create or digitize it. CC BY-SA 3.0 Creative Commons Attribution-Share Alike 3.0 true true This licensing tag was added to this file as part of the GFDL licensing update. Gentle pets and strong watch dogs, GSDs are noble, large, muscular dogs bred for their.
![]() ![]() Stick Em Up features a large variety of weapons to use in your heists, some more serious than others. The combat system also features an intense gore system, which while doesnt overpower the scene provides an entertaining experience through dismemberment and an exaggerated physics-based combat system. Players can utilize different environments to take on tons of enemies, use hostages to pause fighting, and much more. Stick Em Up features a unique combat system that allows players to adapt the game to their style of gunplay. Observe your targets, build your arsenal, take your hostages, and escape with a fat bag of cash. The options for pulling off your heists are nearly endless, alert the police by coming in loud, manipulate your hostages and the clerks into giving you the valuables, use your hostages to keep the police at bay, or be swift and silence all the witnesses before anyone can be called to the scene. Watch as your skills take you from robbing lonely gas stations to the most massive banks. Stickman will dodge and run to stay alive and if weapons dont work anymore, just use your hand to slap and hit the figure. ![]() Choose your weapon, torture the stickman and earn as much money as you can. Your goal is to Shootem using over 30 different weapons and explosives. Stick Em Up, is a game in which you will use your skills, your wits, and your arsenal of guns and explosives to pull off cunning, exciting, and sometimes messy heists. Shoot Em is a funny stickman torture game. DOWNLOAD Stick Em Up (2019) DIRECT LINK - TORRENT - REPACKED Stick'em Up Game - Play online at Y8.com Support for the Flash plugin has moved to the Y8 Browser Install the Y8 Browser to play FLASH Games Download Y8 Browser or FNF: The Ocular Orchestra 2,619 play times Play HTML5 Game Stick'em Up 906,912 play times Requires Y8 Browser Report a bug 85. ![]() ![]() ![]() It emerged from bankruptcy in April 2007 after fending off a hostile takeover from US Airways and its shares were re-listed on the New York Stock Exchange. On September 14, 2005, the company filed for bankruptcy, citing rising fuel costs. In 2003, the company launched Song, a low-cost carrier. Also that year, Delta began an expansion of its international routes into Latin America. In 1997, Delta was the first airline to board more than 100 million passengers in a calendar year. Delta was now the leading airline across the Atlantic. In 1991, it acquired substantially all of Pan Am's trans-Atlantic routes and the Pan Am Shuttle, rebranded as the Delta Shuttle. In 1990, Delta was the first airline in the United States to fly McDonnell Douglas MD-11 jets. In 1987, it acquired Western Airlines, and that same year Delta began trans-Pacific service (Atlanta-Portland, Oregon-Tokyo). In 1981, Delta launched a frequent-flyer program. Trans-Atlantic service began in 1978 with the first nonstop flights from Atlanta to London. In 1965, Delta was the first airline to fly the McDonnell Douglas DC-9.īy 1970, Delta had an all-jet fleet, and in 1972 it acquired Northeast Airlines. In 1964, it launched the Deltamatic reservation systems using computers in the IBM 7070 series. In 1960, it was the first airline to fly Convair 880 jets. In 1959, it was the first airline to fly the Douglas DC-8. In 1953, the company launched its first international routes after the acquisition of Chicago and Southern Air Lines. In 1949, the company launched the first discounted fares between Chicago and Miami. In 1946, the company commenced regularly scheduled freight transport. The company name officially became Delta Air Lines in 1945. Delta moved its headquarters from Monroe, Louisiana, to its current location in Atlanta in 1941. Woolman, and other local investors purchased back the crop-dusting assets of Delta Air Service and incorporated as Delta Air Corporation on December 31, 1930.ĭelta Air Corporation secured an air mail contract in 1934, and began doing business as Delta Air Lines over Mail Route 24, stretching from Fort Worth, Texas, to Charleston, South Carolina. Local banker Travis Oliver, acting as a trustee, C.E. Passenger service ceased in October 1930 when the airmail contract for the route Delta had pioneered was awarded to another airline, which purchased the assets of Delta Air Service. By June 1930, service had extended east to Atlanta and west to Fort Worth, Texas. Passenger operations began on June 17, 1929, from Dallas, Texas, to Jackson, Mississippi, with stops at Shreveport and Monroe, Louisiana. Delta Air Service was incorporated on December 3, 1928, and was named after the Mississippi Delta region. Woolman, general manager and later Delta's first CEO, led a group of local investors to acquire the company's assets. It flew a Huff-Daland Duster, the first true crop duster, designed to combat the boll weevil infestation of cotton crops. The company was founded on March 2, 1925, in Macon, Georgia, before moving to Monroe, Louisiana, in summer 1925. The history of Delta Air Lines begins with the world's first aerial crop dusting operation called Huff Daland Dusters, Inc. Main article: History of Delta Air Lines Early history It is ranked first by revenue for commercially owned airline companies, and 113th on the Fortune 500. It is ranked second among the world's largest airlines by number of passengers carried, passenger-miles flown, and fleet size. ĭelta has nine hubs, with Atlanta being its largest in terms of total passengers and number of departures. As of the end of 2022, it had 90,000 employees. Delta is a founding member of the SkyTeam airline alliance. The airline, along with its subsidiaries and regional affiliates, including Delta Connection, operates over 5,400 flights daily and serves 325 destinations in 52 countries on six continents. One of the world's oldest airlines in operation, Delta is headquartered in Atlanta, Georgia. ![]() ![]() Delta Air Lines is one of the major airlines of the United States and a legacy carrier. ![]() ![]() ![]() The most important thing to remember is that communication is a human right. Some people even use more than one system to help communicate or to supplement speech! Note that every person is different, and there isn’t one AAC that works for everyone. There are options such as eye gaze (using eyes to select things on the screen), laser pointers with communication boards, having an aide help, switches to help choose things (switches can also help people operate toys too!), and tactile options too. Even this post can be considered AAC! Not only that, but there are a lot of ways to help make AAC accessible. ![]() Most people think of apps and high tech, but there are many other forms of AAC too! Using a dry erase board, texting, picture communication symbols, etc – all are forms of AAC. Everyone can benefit from AAC, and AAC is for everyone!Īugmentative and alternative communication is essentially any communication that doesn’t involve mouth words. Some people use it full time, while others use it to supplement speech when mouth words alone aren’t as effective for communication. It’s important to note that people can use AAC for a variety of reasons: autism, aphasia, cerebral palsy, traumatic brain injury, etc. I wanted to put together a sort of guide to different types and options for augmentative and alternative communication (AAC). The caption says “All about AAC: A Beginner’s Guide to Augmentative and Alternative Communication Options.” Underneath is the author’s name, Courtney Johnson, this website, and the Instagram handle at just keep stimming. Note: This post is accurate as of its most recent update – and will be updated periodically when I’m able to!Ī square photo with a cream color background, with sunflowers and leaves in the corners. ![]() ![]()
![]() It is not possible to hide the feature from an Android or iOS mobile device when utilizing Instagram. If you want to continue taking questions from your followers, you need to enable comments The chat section will disappear once you finish the steps above. If you want to take a few questions from your fans while you are live, you will need to enable comments on your Instagram post. Turning off the comment section can be found in the menu that opens.Tap the three dots near the comment option after going live.Once you do this, all previous comments will disappear, and once you turn off comments, comments made before you turn off comments, you will no longer be able to see them. When you, as the content creator, are holding an Instagram live session, you can choose to hide chats by disabling the comments. Hide Chat on Instagram Live as Content Creator ![]() In such a case, as explained in the following sections, there are methods you can use to disable the comments, if you have found the comments distracting and you do not wish to continue using them. If you enable the chat section during Instagram live sessions, you may find that the program becomes unproductive as you cannot handle too many questions while still staying on top of the program.įor this reason, hiding the chat section and finishing the Instagram live session might be a good idea. When you become a celebrity on Instagram, you have a substantial following. If you hide chat, you will be able to avoid negative chats and angry comments. If your Instagram session is designed to promote your business, negative chats might ruin the session by scaring people off. It is essential to hide chat where you can avoid such negativity and angry comments. Some people join sessions in order to achieve their goal, and experiencing spam messages may frustrate them. In case you are experiencing spam messages while you are participating in a live stream session on Instagram, it would be a good idea for you to turn off comments. Some of the most common reasons are the following. For this reason, it is essential to hide the chat once in a while and concentrate on your conversation.ĭuring live sessions on Instagram, there are many reasons why people choose to hide the chat during the session. ![]() You may get nasty comments from some people that may kill your interest in continuing the session. When someone goes live on Instagram, they can decide whether to allow comments or turn them off. A fantastic feature of Instagram is Instagram live, which has been developed for the purpose of allowing its users to interact with their fans. ![]() ![]() Valvar aortic stenosis is generally caused by incomplete or abnormal development of the aortic valve (bicuspid or unicuspid morphology, poorly defined cusps, hypoplastic aortic annulus). A prominent muscle bundle (muscle of Moulaert) on the left ventricular free wall can also contribute to LVOTO by projecting into the left ventricular outflow tract (LVOT). Subvalvar LVOTO is related to the posterior and leftward malalignment of the conal or outflow septum, the most commonly associated anomaly in IAA. Several anatomic substrates for LVOTO can be identified in IAA at a subvalvar, valvar, or supravalvar level, or as a combination of the three (multilevel stenosis). Despite excellent peri-operative survival, successful IAA repair can be complicated by left ventricular outflow tract obstruction (LVOTO), which may be present preoperatively or may (re-)occur during follow-up. The preferred treatment of IAA consists of a single-staged biventricular repair with closure of the ventricular septal defect (VSD) and reconstruction of the arch. IAA is defined as a lack of luminal continuity between the ascending and the descending thoracic aorta. Interrupted aortic arch (IAA) is a rare congenital lesion comprising approximately 1.5% of all congenital heart disease. In patients with a borderline left ventricular outflow tract that undergo a primary repair, these (pre-) operative predictors can provide guidance for optimal surgical decision-making and for close monitoring during follow-up of patients at increased risk for developing left ventricular outflow tract obstruction after corrective surgery. Anatomic and surgical risk factors for left ventricular outflow tract obstruction were the presence of an aberrant right subclavian artery, use of a pulmonary homograft or polytetrafluoroethylene interposition graft for aortic arch repair, and the presence of a small- or medium-sized ventricular septal defect. Manifestation of postoperative left ventricular outflow tract obstruction was associated with a smaller pre-operative size of the aortic root (sinus of Valsalva), sinotubular junction, and aortic annulus. Postoperative left ventricular outflow tract obstruction requiring an intervention was common, with an incidence ranging between 14 and 38%. From the 44 potentially relevant studies, eight studies met the inclusion criteria. Studies that reported echocardiographic and/or clinical predictors for left ventricular outflow tract obstruction in infants that underwent biventricular repair of interrupted aortic arch were included. A systematic search of the literature was performed across the PubMed and EMBASE databases. The aim of this review is to summarize reported risk factors for left ventricular outflow tract obstruction after corrective surgery for interrupted aortic arch. Identification of patients at risk for obstruction is important to facilitate clinical decision-making and monitoring during follow-up. Left ventricular outflow tract obstruction is an important complication after interrupted aortic arch repair and subsequent interventions may adversely affect survival. ![]() ![]() ![]() Make your controller SMART with EPA WaterSense certification by adding the LNK WiFi module and a WR2 rain sensor. The ESP-TM2 provides the Extra Simple Programming interface you are familiar with in a controller that is built to last!īest of all, you can upgrade the ESP-TM2 into a WiFi-enabled controller by simply installing a new LNK WiFi Module, without having to replace the entire unit. Additional modules are sold separately and can be found by shopping at Sprinkler Warehouse. The base model controller includes the base module which allows for 4 stations. ![]() 7 Items Sort By Bundle - ESP-TM2 - 12 Station Indoor/Outdoor 120V Irrigation Controller & LNK WiFi Module 551. The Rain Bird ESP-Me 4 station wifi ready indoor controller is module by design and can be expanded with the use of the ESPSM3 and ESPSM6 expansion modules. Indoor and outdoor irrigation timer models are also available. WiFi access for real-time alerts and automatic weather adjustments that can save water and money Controller access through the Rain Bird mobile app with or without WiFi Check out our new podcast episode about the unique RC2 controller and how it is an absolute game-changer for the irrigation industry. With the flexibility of 3 programs and 4 start times available per program, you can tailor your watering schedule to your landscape’s needs. Rain Bird timers are easy to program and include zone-based timers, modular timers, and weather-based smart timers. Building upon Rain Bird’s legacy of The Intelligent Use of Water®, this controller offers simple water saving features that you will actually use. The ESP-TM2 irrigation controller is the perfect option for basic residential solutions. Simple, Flexible and Reliable for Residential Applications ![]() |